Liquid Chromatography of Synthetic Polymers

         
                           
Scientific Federation   invites all the participants from all over the world to attend “ World  Conference on Analytical and Bioanalytical  Chemistry” during July23-24, 2018 in Barcelona, Spain which presents talks and presentation from highly eminent persons and exhibition of Standard Companies. The conference aims to bring the participants from all over the world to share their emerging ideas and interest in Analytical chemistry. The conference provides the research works of Analytical chemistry expertise from various scientific backgrounds and the same can be perceived by young researchers and students. Analytical Chemistry Conferences mainly aims to promulgate knowledge in Analytical & Bio analytical Chemistry.The main theme of the Analytical Chemistry is Understanding the Importance and Impacts of Analytical & Bioanalytical Chemistry. Analytical chemistry is a field of science in which chemists study the structure, properties, composition, reactions to create new molecules and explore the properties of existing compounds. The conference covers the wide range of expertise in the field of chemistry encouraging researchers for presentation, communication and discussion of research results carried out in academia and industry. It will be a benchmark in the field of Analytical chemistry where every researcher, scientist, professors, deans, will be approaching with innovative ideas to improve the field of analytical chemistry.


                            

                       
Scientific Federation is into scientific acceleration by bringing the world class researchers, to join in the field of Analytical and Bioanalytical Chemistry. It provides a platform to have open interactions among field experts at WCABC-2018.  Analytical Chemistry is the study of the separation, identification, and quantification of the chemical components of natural and artificial materials. Sessions included in World Conference on Analytical and Bioanalytical Chemistry are Novel Approaches to Analytical and Bioanalytical Methods, Analytical and Bioanalytical Methodology, Chromatographic Techniques, Electrophoresis, Forensic Analysis, Environmental Analytical aspects, Single Molecule Imaging and Spectroscopy, Advances in Separation Techniques, Advancements in Mass Spectrometry, Applications of Analytical and Bioanalytical Methods, Advancements in Analytical and Bioanalytical Methods, Miniaturization, Thermal Analysis and Glycomics , Regulatory Issues and Bio safety Challenges in Bioanalysis, Electrochemical analysis, Analytical Instrumentation and Equipment, Analytical Strategies for Biosimilars. You can choose any topic including these sessions and also you can choose any topic related to Analytical and Bioanalytical Chemistry.

                       


Join in our congress and understand what other eminent speakers in your field are working on and hence gaining more skills and knowledge as a researcher. The Conference that helps you to get to know other scholars and to be known in academic circles is to convene prearranged panels for the big academic conferences. In this Conference Students also have the opportunity to explore the leading edge of the discipline, and making connections in the scientific community can be of huge benefit for an undergraduate interested in embarking on a scientific career. Although the advent of the e-mail has largely supplanted the necessity of face-to-face conversations, this cross-fertilization of ideas still takes place during academic conferences, where researchers present their projects, discuss their findings, network with potential collaborators, and socialize with their peers. This can help students to identify potential projects, laboratories, and institutions that they would like to work with in the future. Send your abstract and confirm your slot for presenting your research thoughts. Abstract submission Deadline is June 31st, 2018


ForAbstractSubmission:




                       

Dusan Berek, Prof, PhD, DSc Employed at Polymer Institute, Slovak Academy of Sciences in Bratislava. Served as elected member of the Presidium of the Slovak Academy of Sciences, President of the Slovak Chemical Society, Chairman of the Czecho-Slovak and Slovak National Committee of Chemistry for IUPAC. Corresponding member of the Central European Academy of Sciences and member of the Learned Society of the Slovak Academy of Sciences. Author or co-author of two monographs and 300+ scientific papers in extenso published in refereed periodicals, proceedings and chapters of books, as well as 60+ patents (four of them were licensed) - cited more than 3,000x. Presented over 130 invited plenary, key and main lectures, as well as over 900 regular lectures and poster contributions on symposia and conferences, as well as during lecturing tours to over fourty countries. Elected „Slovak scientist of the year 1999“, and „Slovak innovator of the year 2002“ 


High performance liquid chromatographic (HPLC) methods represent an important practical tool for molecular characterization of synthetic polymers. Mean molar mass (MM) and molar mass distribution (MMD) of linear and branched homopolymers can be readily determined by gel permeation (size exclusion) chromatography (GPC/SEC). GPC/SEC also provides several other useful data on polymers such as limiting viscosity numbers, constants of viscosity law, sizes of macromolecules in solution - and even on extent of their preferential solvation in mixed solvents. Recent progress in GPC/SEC comprises improved instrumental hardware and data processing procedures. The ultra-high pressure GPC/SEC enables significant acceleration of analyses, which is especially important in combinatorial material chemistry and in polymer production control. Still, further improvements of the GPC/SEC method are needed comprising its hardware, especially columns and detectors, as well as standardization of sample preparation, measurement, and data processing. GPC/SEC exhibits excellent intra-laboratory repeatability, which evokes a notion of its high reliability. However, recent series of the round robin tests revealed surprisingly poor inter-laboratory reproducibility of results. Evidently, accuracy of many GPC/SEC results may be rather limited. Moreover, GPC/SEC hardly enables precise molecular characterization of complex polymer systems, which possess more than one distribution in their molecular characteristics. Typically, polymer mixtures, copolymers and functional polymers exhibit besides MMD also distribution in their chemical structure. To assess above distributions, new HPLC procedures are developed. These make use the controlled combinations of entropic (exclusion) and enthalpic (interaction) retention mechanisms within one column or in a series of independent separation systems. Enthalpic retention mechanisms in HPLC of synthetic polymers include adsorption, partition and phase separation. The resulting approaches are denoted “coupled polymer HPLC” and “two-dimensional polymer HPLC”. We shall review recent progress and problems in GPC/SEC, as well as in coupled, and two-dimensional polymer HPLC procedures, and outline anticipated future development.







                            

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Get registered for our prestigious conference.
Looking Forward to see you all at WCABC-2018 in Spain.!!!


Bioanalytical Methods


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Dr. Shyamal Kumar Chattopadhyay will be participating at the World Conference on Analytical and Bioanalytical Chemistry held by Scientific Federation. Dr. Shyamal Kumar Chattopadhyay has completed his PhD from Indian Association for the Cultivation of Science, Jadavpur, India in 1988 and was a Brain-Pool vesting scientist at KRICT, South Korea during 2006-2007. He is a faculty at IIEST, Shibpur since 1989 and is Professor since July 2006. He has published more than 80 papers in reputed journals. Dr. Shyamal Kumar Chattopadhyay is going to talk on ‘Chemodosimetric detection of HOCl/OCl− using a Ni(II) complex as a ratiometric fluorescent probe and its real applications.’ A brief summary is presented here.

Vitamin B6 cofactor derived ligand H2Bala-pydx was synthesized by condensation of pyridoxal hydrochloride with beta-alanine. Its complex with Ni(II) isolated and characterized using analytical and spectroscopic techniques. X-ray crystal structure confirmed the formulation of the compound as [Ni(HBala-pydx)2]·2H2O·CH3OH (NHBP) . The Ni(II) complex NHBP can be used as a fluorescent chemodosimeter and it serves as a highly sensitive and selective fluorescent sensor for the detection of HOCl/OCl− at pH 7.4. The reaction based approach towards the metal complex makes the fluorescent probe highly effective for detection of OCl− in tap water and living cells. It is also shown a simple low cost dip-stick can be designed using this complex for qualitative/ semi-quantitative detection of HOCl/OCl−. The detection is highly specific in presence of other ROS.
For more information : http://www.scientificfederation.com/analytical-chemistry-2018/

Miniaturization


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Dr. Imran Ali will be participating at the World Conference on Analytical and Bioanalytical Chemistry held by Scientific Federation Prof. Imran Ali PhD, FRSC, C Chem, London (UK) is a world recognized academician and researcher. He completed his Ph.D. from Indian Institute of Technology Roorkee, Roorkee, India. Prof. Ali is known globally due his great contribution in separation science, chiral drugs development and water treatment. He has published more than 380 papers in reputed journals including papers in Nature and Chemical Reviews of more than 41 impact factors. He has also written five books published by Marcel Dekker, Inc., USA; Taylor & Francis, USA; John Wiley & Sons, USA; John Wiley & Sons, UK; Elsevier, The Netherlands. His citation is 13,500 with H index 48 and i10-index 174. Dr. Imran Ali is going to talk on

‘Nano chromatography and nano capillary electrophoresis: Need of this century.’ A brief summary is presented here.

In spite of the curing properties of the drugs, these remain in our body tissues at very low concentrations for long time; leading to serious side effects. Similarly, some environmental pollutants exist at very low concentration in the earth’s ecosystem. The normal analytical instruments are not capable to detect them. Hence, we consider these species as absent, which is an illusion to the scientists and the society. The concentrations of some hormones, RNAs, DNAs, antibodies and other proteins are very low. Availability of infant plasma and cerebrospinal fluids is very poor. The proteomics and genomics researches are extremely difficult and need miniaturization of the separation techniques. Besides, the increasing economic pressure of the costly chemicals is a big issue globally nowadays. In view of these facts, there is big demand of microscale separations with low detection limits. Due these facts the micro-total-analysis system (µ-TAS) has been developed and is being used in few laboratories of the world. These are nano liquid chromatography (NLC) and nano capillary electrophopresis (NCE) techniques. The proposed lecture will highlight the importance of these techniques with special emphasis onthe fabrication of microchip, instrumentation of NLC and NCE, detection,sample preparation, analyses and future perspectives.
For more information : http://www.scientificfederation.com/analytical-chemistry-2018/

Advancements in Analytical and Bioanalytical Methods


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Dr. Heinz Siesler will be participating at the World Conference on Analytical and Bioanalytical Chemistry held by Scientific Federation. Dr. Heinz Siesler is a Professor of Physical Chemistry at the University of Duisburg-Essen, Germany, since 1987. His main research interests focus on the application of vibrational spectroscopy to chemical and polymer research and quality control. He has written 236 publications (including four monographs) and presented more than 275 lectures worldwide. He received the 1994 EAS Award, the 2000 Tomas Hirschfeld Award and the 2003 Buechi Award in near-infrared spectroscopy and he is a Fellow of the Society for Applied Spectroscopy (USA).He held guest professorships in France (1992), Japan (2000-2010) and Austria (2008-2017) and prior to his present academic position he gained extensive industrial experience from 1974-1987 in the Corporate R&D Department of Bayer AG, Germany. He also worked as lecturer at the University of the Witwatersrand, Johannesburg, South Africa (1972-1974) and as post-doc at the University of Cologne (1970-1972), Germany, after receiving his PhD in Chemistry from the University of Vienna, Austria, in 1970. Dr. Heinz Siesler is going to talk on ‘Handheld Vibrational Spectrometers: State-of-the-Art Instruments and their Realistic Applications.’ A brief summary is presented here.

Over the last decades vibrational spectroscopy (Raman, near-infrared, mid-infrared) is characterized by a multiplicity of hard- and software developments such ashyperspectral imaging, coupling with light-fiber optics and chemometric evaluation routines, but the application of these techniques so far remained a domain for scientists. In contrast, the recent developments of miniaturized, handheld spectrometers show promise for useful every-day-life applications by non-expert user environments. Inside the molecular spectrometer market, the fastest growing segment is miniature spectrometers and this market is expected to reach $ 300m by 2021.This significant growth will not only be based on a wider adoption of spectrometers for industrial process control and in-the-field/on-site testing but also on every-day-life consumer applications like food testing. The presentation will provide an overview on the building principles of the most recently introduced handheld vibrational spectrometers and critically highlight their performance and potential by means of selected application examples.

Applications of Analytical and Bioanalytical Methods


 
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Dr. Vakhtang Barbakadze will be participating at the World Conference on Analytical and Bioanalytical Chemistry held by Scientific Federation. Dr. Vakhtang Barbakadze has completed his Ph.D. and D.Sci. in 1978 and 1999 from Institute of Organic Chemistry, Moscow, Russia and Institute of Biochemistry and Biotechnology, Tbilisi, Georgia, respectively. He is the head of department of plant biopolymers and chemical modification of natural compounds at the Tbilisi State Medical University I.Kutateladze Institute of Pharmacochemistry. 1996 and 2002 he has been a visiting scientist at Utrecht University (faculty of pharmacy), The Netherlands, by University Scholarship and The Netherlands organization for scientific research (NWO) Scholarship Scientific Program, respectively. He has published more than 92 papers in reputed journals. Dr. Vakhtang Barbakadze is going to talk on ‘Structure characterization of plant macromolecule – prospective therapeutic agent’ A brief summary is presented here.

The 13C NMR experiment of water-soluble high-molecular preparations from different species of Boraginaceae family was carried out and simulated 13C NMR spectrum was calculated for 2-hydroxy-3-(3',4'-dihydroxyphenyl)-propionic acid residue (I) of the corresponding polyether using ACD/CNMR Version 1.1 program. Signal positions in the 13C NMR spectrum of this hypothetical structure (I) coincided satisfactory with the experimental values. According to 13C, 1H NMR, APT, 2D heteronuclear 1H/13C HSQC and 2D DOSY experiments the main structural element of these preparations was found to be a regularly substituted by 3,4-dihydroxyphenyl and carboxyl groups polyoxyethylene backbone, namely poly[oxy-1-carboxy-2-(3,4-dihydroxyphenyl)ethylene] or poly[3-(3,4-dihydroxyphenyl)glyceric acid] (PDPGA). The synthesis of racemic monomer of PDPGA 2,3-dihydroxy-3-(3,4-dihydroxyphenyl)propionic acid (DDPPA) and its enantiomers (+)-(2R,3S)-DDPPA and (–)-(2S,3R)-DDPPA was carried out via Sharpless asymmetric dihydroxylation of trans-caffeic acid derivatives using a potassium osmate catalyst and enantiocomplementary catalysts cinchona alkaloid derivatives (DHQ)2-PHAL and (DHQD)2-PHAL as chiral auxiliaries. The opposite configuration of both enantiomers was confirmed by measurements of the optical rotation (+)/(–)-values and circular dichroism spectra. The determination of enantiomeric purity was performed by HPLC analysis. PDPGA and DDPPA exerted anti-cancer efficacy in vitro and in vivo against human prostate cancer (PCA) cells via targeting androgen receptor, cell cycle arrest and apoptosis without any toxicity, together with a strong decrease in prostate specific antigen level in plasma. However, our results showed that anticancer efficacy of PDPGA is more effective compared to its synthetic monomer. Overall, this study identifies PDPGA as a potent agent against PCA without any toxicity, and supports its clinical application.
For more information : http://www.scientificfederation.com/analytical-chemistry-2018/

Analytical and Bioanalytical Methodology


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Dr. Ramanujachary will be participating at the World Conference on Analytical and Bioanalytical Chemistry held by Scientific Federation. Dr. Ramanujachary has completed his PhD from Indian Institute of Technology, and postdoctoral studies from Rutgers University, NJ, University, USA. He is currently working as a professor at the Department of Chemistry and Biochemistry at Rowan University. He has published more than 220 papers in reputed journals and holds several patents. Dr. Ramanujachary is going to talk on ‘Analytical Methods for the Conversion of Wasted Biomass to Value Added Chemicals’ A brief summary is presented here.

Rapid depletion of non-renewable fossil resources is posing an imminent threat to the energy and supply of fine chemicals that are vital to the global economy. Conversion of Biomass to value added chemicals has been on the forefront of strategies that are focused on eliminating our dependence on non-renewable resources such as coal and petroleum. Studies in the last two decades have resulted in the efficient conversion of corn to ethanol, at the same time escalating the corn prices beyond the reach of poor. In our research we have shifted our focus to the utilization of wasted biomass which does not interfere with the human or animal food chain. Use of sugar cane bagasse, switch grass, corn stover and wood from natural forests has been contemplated for bio-mass conversion to renewable fuels/chemicals. In this context, there exists a dire need to develop novel analytical separation methods and cost-effective materials to increase the efficiency of the conversion processes. For the conversion we have designed and developed novel catalytic materials with the efficiencies superior to those that currently exist. They have conducted the research in several phases in which the biomass is pretreated and the cellulose component has been separated from the lignin using mild and non-corrosive acids. The cellulose is subsequently converted to sugars which are broken down to glucose and fructose. Dehydration of sugars to hydroxymethyl furfural (HMF) is achieved by a novel catalyst featuring both Lewis and Bronstead acid sites. The presentation will summarize the importance of analytical techniques in the determination/separation of various products and opportunities for exploring inorganic materials for the production of value added chemicals and fuels.
For more information : http://www.scientificfederation.com/analytical-chemistry-2018/

Electrochemical analysis



Scientific Federation invites all the participants from all over the world to attend World Conference onAnalytical & Bio analytical Chemistry which will be held on July 23-24, 2018 at Barcelona, Spain. Which includes Keynote presentations, Oral talks, Poster presentations and Exhibitions.

Electrochemistry is the study of techniques that use electrical stimulation to analyze the chemical reactivity of a system. More specifically, it analyzes the loss and gain of electrons i.e. the oxidation and reduction mechanisms in a reaction. Oxidation and reduction reactions are called redox reactions- these provide vital information related to the kinetics, concentration, mechanism of reaction, and chemical status of the reactants in solution.

It is very helpful in many applications including the study of neurotransmitter behavior and polymerizations reactions. Electrochemistry is different from spectroscopy as electrochemical techniques analyze a different set of parameters.

It is a qualitative and quantitative methods of analysis based on electrochemical phenomena occurring within a medium or at the phase boundary and related to changes in the structure, chemical composition, or concentration of the compound being analyzed

Electroanalytical methods measure the potential volts and current amps in an electrochemical cell containing the analyte. In this the methods can be categorized according to which aspects of the cell are controlled and which are measured. The three main categories are potentiometry it means the difference in electrode potentials is measured, coulometry the cell's current is measured over time, and voltammetry the cell's current is measured while actively altering the cell's potential.